Atomic Structure

1. What is an Atom?

An atom is the smallest particle of an element that retains the properties of that element.


2. Subatomic Particles

ParticleSymbolRelative MassRelative ChargeLocation
Protonp⁺1+1Nucleus
Neutronn10Nucleus
Electrone⁻1/1836-1Orbitals/Shells

3. Atomic Number (Z) and Mass Number (A)

  • Atomic Number (Z): Number of protons in an atom.
  • Mass Number (A): Total number of protons + neutrons.

Example:

  • Carbon has 6 protons and 6 neutrons.
  • Atomic number = 6, Mass number = 12
    So, we write:
    ₆¹²C

4. Isotopes

Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons.

Example:

  • ₁₇³⁵Cl and ₁₇³⁷Cl are isotopes of chlorine.
    Both have 17 protons, but 18 and 20 neutrons respectively.

🔹 Uses of Isotopes:

  • Carbon-14: Carbon dating
  • Cobalt-60: Cancer treatment
  • Iodine-131: Thyroid treatment

5. Electronic Configuration

Electrons are arranged in energy levels or shells around the nucleus:

  • 1st shell: holds max 2 electrons
  • 2nd shell: holds max 8 electrons
  • 3rd shell: holds max 8 electrons (for O level)

Examples:

ElementAtomic NumberElectron Configuration
H11
He22
Li32,1
C62,4
O82,6
Na112,8,1
Cl172,8,7

6. Groups and Periods in the Periodic Table

  • Group: Number of electrons in the outer shell
  • Period: Number of electron shells

Example:

  • Na (2,8,1) → Group 1, Period 3

7. Ions

When atoms lose or gain electrons, they become ions.

  • Cation: A positive ion (loss of electrons)
  • Anion: A negative ion (gain of electrons)

Examples:

  • Na → Na⁺ + e⁻ (Cation)
  • Cl + e⁻ → Cl⁻ (Anion)

8. Noble Gases and Stability

  • Group 18 (Noble Gases) have full outer shellsvery stable and unreactive
  • Atoms tend to gain, lose, or share electrons to achieve noble gas configuration.

9. Relative Atomic Mass (Ar)

The average mass of all the isotopes of an element compared to 1/12 of a carbon-12 atom.

Example:
Chlorine has two isotopes:

  • 75% ³⁵Cl
  • 25% ³⁷Cl

Ar=[(75×35)+(25×37)]/100=[2625+925]/100=35.5


10. Common Misconceptions

  • Electrons do not orbit in fixed paths like planets — the modern model uses orbitals.
  • Mass number includes only protons and neutrons, not electrons.
  • Isotopes have the same chemical properties, but different physical properties.

✍️ Practice Questions

  1. What is the electron configuration of:
    • (a) Magnesium (Z=12)
    • (b) Oxygen (Z=8)
  2. Calculate the relative atomic mass of boron given:
    • 20% of boron is ¹⁰B
    • 80% is ¹¹B
  3. How many protons, neutrons, and electrons are in:
    • (a) ₈¹⁶O
    • (b) ₁₁²³Na⁺

📌 Summary

  • Atoms are made of protons, neutrons, and electrons.
  • Atomic number = protons; Mass number = protons + neutrons.
  • Isotopes are atoms with same protons but different neutrons.
  • Electron configuration helps identify group and period in the periodic table.
  • Ions form to achieve noble gas configuration.
  • Relative atomic mass is weighted average of isotopes.

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